Carbon Rich Compounds II

Macrocyclic Oligoacetylenes and Other Linearly Conjugated Systems

Carbon Rich Compounds II

Macrocyclic Oligoacetylenes and Other Linearly Conjugated Systems

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The definition of Carbon Rich Compounds applied in this as in the previous volume (TCC Volume 196) of this series on the same general topic comprises carbon skeletons with a carbon to hydrogen ratio of 1:(kleiner gleich 1), which ultimately implies all-carbon compounds (i.e. carbon allotropes). The current volume covers modern methods for the coupling - mostly metal catalyzed - of subsystems consisting of double bonds, cyclopropyl groups, arenes, and metal-complexed pi-systems with acetylene and diacetylene units. The resulting structures range from macrocycles, including those with all sorts of linkers between the acetylene and diacetylene units, to conducting polymers and light-emitting materials. Wherever appropriate, chemical transformations of these intriguing compounds and materials are discussed as well.

Macrocyclic Structurally Homoconjugated Oligoacetylenes: Acetylene- and Diacetylene-Expanded Cycloalkanes and Rotanes
Cyclic and Linear Acetylenic Molecular Scaffolding
Macrocyclic Oligo(phenylacetylenes) and Oligo(phenyldiacetylenes)
Carbon-Rich Molecular Objects from Multiply Ethynylated ?-Complexes
Oligo- and Polyarylenes, Oligo- and Polyarylenevinylenes.
ISBN 978-3-540-65301-1
Article number 9783540653011
Media type Book
Edition number 1999
Copyright year 1999
Publisher Springer, Berlin
Length XI, 227 pages
Illustrations XI, 227 p. 4 illus.
Language English