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PF3, (CH3)3SiCl - (CH3)3SiF, and RC(O)Cl - RC(O)F. Others include the conversion of (C6H5)3P into (C6H5)3PF2 and of (R3NC(S)S)2 into R2NCF3, R=alkyl. In organic chemistry, fluorides are easily accessible from alcohols, geminal fluorides RR'CF2 from the respective aldehydes or ketones, and acyl fluorides RC(O)F from carboxylic acides by using DAST. Because DAST is easy to handle and gives clean reactions in syntheses, this Gmelin volume devotes much space to the description of the chemical and physical properties od DAST.
ISBN 978-3-662-06365-1
Article number 9783662063651
Media type Book
Edition number 8. Aufl.
Copyright year 2013
Publisher Springer, Berlin
Length XXXI, 487 pages
Illustrations XXXI, 487 p. 2 illus.
Language English