In the last few years a large repertoire of methods for the activation of unreactive organic functionalities and for their use in organic synthesis has been developed. In this volume, areas ranging from the activation of C-H bonds to the chemical transformation of dinitrogen are authoritatively discussed by leading experts in the field. To activate means to be able to cleave otherwise inert chemical bonds. The cleavage and formation of chemical bonds is fundamental to organic synthesis; these new activation methodologies make hitherto infeasible reactions extremely easy and create new opportunities for innovative organic transformations, for both industry and academia. This is the first book that provides a thorough and timely coverage of both inorganic and organic synthetic aspects of bond activation, thus giving a broad overview of the field and allowing both inorganic and organic chemists ready access to the methodologies involved.

A General Survey and Recent Advances in the Activation of Unreactive Chemical Bonds by Metal Complexes

Activation of C-H Bonds: Stoichiometric Reactions
Activation of C-H Bonds: Catalytic Reactions
Catalytic Activation of Methane and Ethane by Metal Compounds
Cleavage of Carbon-Carbon Single Bonds by Transition Metals
Activation of Si-Si Bonds by Transition-Metal Complexes
Activation of C-O Bonds: Stoichiometric and Catalytic Reactions
Activation of Otherwise Unreactive C-Cl Bonds
Activation of the N-N Triple Bond in Molecular Nitrogen: Toward its Chemical Transformation into Organo-Nitrogen Compounds
Metal Reagents for Activation and Functionalization of Carbon-Fluorine Bonds.