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In this book the first three chapters outline the chemistry of nickel and heme largely associated with anaerobic life and believed to represent reactions which took place some 3-4x109years ago. Nickel has disappeared from the chemistry of man. The fascinating detail of the "primitive" catalysts is of interest to industrial society since very simple feed-stock is used, hydrogen, carbon monoxide and sulphate for example. The fourth chapter switches attention to a metal which became valuable later in evolution, copper, and which is involved with the use of dioxygen. It also has extremely interesting catalytic sites in enzymes. The essence of the volume lies in an appreciation of metallo- enzymes and their changing roles as the environment changed.

Biological Nickel
Nickel in F430
Hemeproteins in anaerobes
Evolutionary aspects of copper binding centers in copper proteins.
ISBN 978-3-540-63548-2
Artikelnummer 9783540635482
Medientyp Buch
Copyrightjahr 1997
Verlag Springer, Berlin
Umfang X, 209 Seiten
Abbildungen X, 209 p. 83 illus., 12 illus. in color.
Sprache Englisch