1;Preface;62;Contents;83;Chapter 1 Introduction to Zeolite Science and Catalysis;123.1;1.1 General Trend of the Zeolite Acid Catalyst: Species, Structure, and Industrial Application;123.2;1.2 Property of Zeolite Catalyst: Acidity, Shape Selectivity, and Loading Property;163.3;1.3 Intention of the Publication with the Background of the Zeolite Chemistry;173.4;References;194;Chapter 2 Solid Acidity of Zeolites;204.1;2.1 Multiple Characterization Techniques;204.1.1;2.1.1 Physical Properties;204.1.2;2.1.2 Chemical Properties;214.2;2.2 Fundamentals for the TPD of Ammonia;224.2.1;2.2.1 Experimental Apparatus of the TPD Method;224.2.2;2.2.2 Identification of the Desorption, l- and h-Peaks;244.2.3;2.2.3 Identification of Ammonia Desorbed from Y Zeolite;254.3;2.3 Theory for the TPD of Ammonia;264.3.1;2.3.1 Conditions of the Equilibrium;264.3.2;2.3.2 Derivation of a Fundamental Equation;284.3.3;2.3.3 Determination of .H and Constancy of .S (Desorption);304.4;2.4 Practical Measurements of Ammonia TPD;314.4.1;2.4.1 Curve Fitting Method to Measure the Strength of Acid Site;314.4.2;2.4.2 .H on Various Zeolites with Different Concentrations of Acid Site;324.5;2.5 Number of Acid Sites on Various Zeolites;354.5.1;2.5.1 Number of Acid Sites Correlated with Al Concentration;354.5.2;2.5.2 In Situ and Ex Situ Prepared H-type Zeolites;374.6;References;385;Chapter 3 IRMS-TPD Measurements of Acid Sites;395.1;3.1 Measurement Method;395.1.1;3.1.1 What Is Obtained from the TPD Measurement;395.1.2;3.1.2 Experimental Methods;395.1.3;3.1.3 Required Corrections, IR Band Position and S;415.2;3.2 Proton Form Zeolite;425.2.1;3.2.1 H-Mordenite;425.2.2;3.2.2 H-Y and H-Chabazite;445.3;3.3 Modified Zeolites;495.3.1;3.3.1 Multivalent Cation-Modified Zeolite;495.3.2;3.3.2 Ultrastable Y (USY) Zeolite;515.4;3.4 Distribution of Brønsted Acid Sites Dependent on the Concentration;535.5;3.5 Relationship Between Stretching Frequency and Ammonia Desorption Heat of OH Group;555.6;3.6 Distorted Structure of Zeolite and Related Material with Lewis Acidity and Broad Distribution of Acid Strength;575.7;3.7 Measurements of Metal Oxide Overlayer;625.8;3.8 Extinction Coefficients of NH4+ and NH3 Adsorbed on Brønsted and Lewis Acid Sites, Respectively;655.9;References;696;Chapter 4 DFT Calculation of the Solid Acidity;706.1;4.1 DFT Calculation;706.1.1;4.1.1 DFT Calculation Applied to the Study on Brønsted Acidity;706.1.2;4.1.2 Embedded Cluster and Periodic Boundary Conditions;716.2;4.2 Application to Chabazite, a Simple Zeolite;726.2.1;4.2.1 Brønsted Acid Sites in Chabazite Based on the Models Within the Periodic Boundary Conditions;726.2.2;4.2.2 Brønsted Acid Site in an Embedded Cluster Model;746.3;4.3 Application to Other Zeolites;746.3.1;4.3.1 FAU, MOR, and BEA Calculated Under the Conditions of the Embedded Cluster and the Periodic Boundary;746.3.2;4.3.2 MFI, FER, and MWW Calculated Under the Embedded Cluster Model;766.4;4.4 Modified Zeolites;786.4.1;4.4.1 Divalent Cation-Exchanged Y Zeolites Based on the Embedded Cluster Model;786.4.2;4.4.2 Modified Brønsted OH in Y Zeolite Based on the Periodic Boundary Conditions;806.5;4.5 Dependence of Brønsted Acid Strength on Local Geometry;816.6;References;877;Chapter 5 Catalytic Activity and Adsorption Property;887.1;5.1 Paraffin Cracking;887.1.1;5.1.1 Evaluation of Intrinsic Activity of Acid Site;887.1.2;5.1.2 Dependence of Activity on Acid Strength;907.1.3;5.1.3 Thermodynamic Description on Correlation Between Activation Energy and Ammonia Desorption Heat;957.1.4;5.1.4 Behavior of Acid Sites in 8- and 12-Rings of Mordenite;977.2;5.2 Adsorption of Aromatic Hydrocarbons;987.3;5.3 Friedel--Crafts Alkylation on Ga-MCM-41;1027.4;5.4 Amination of Phenol into Aniline on Ga/ZSM-5;1067.5;References;1098;Chapter 6 CVD of Silica for the Shape Selective Reaction;1118.1;6.1 Reactants and Products Shape Selectivity, Concept and Definition;1118.2;6.2 Chemical Vapor Deposition of Si