Conducting Polymers

A New Era in Electrochemistry

Conducting Polymers

A New Era in Electrochemistry

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The discovery of polymers with variable conductivity brought forth a paradigmatic change in chemistry and in other branches of science and technology. Electrochemistry has played a central role in the preparation, characterization and application of these new materials. This book is a systematic survey of the knowledge accumulated in this field in the last thirty years. It includes thermodynamic aspects, the theory of the mechanism of charge transport processes, the chemical and physical properties of these compounds, the techniques of characterization, the chemical and electrochemical methods of synthesis as well as the application of these systems. The book contains a compilation of the polymers prepared so far and covers the relevant literature.

1;Preface;6 2;Contents;7 3;Chapter 1 Introduction;11 4;Chapter 2 Classification of Electrochemically Active Polymers;16 4.1;2.1 Redox Polymers;16 4.2;2.2 Electronically Conducting Polymers (Intrinsically Conducting Polymers-ICPs);23 4.3;2.3 Electronically Conducting Polymers with Built-In or Pendant Redox Functionalities;49 4.4;2.4 Copolymers;55 4.5;2.5 Composite Materials [741-776];57 4.6;References;58 5;Chapter 3 Methods of Investigation;75 5.1;3.1 Electrochemical Methods;76 5.2;3.2 In Situ Combinations of Electrochemistry with Other Techniques;96 5.3;3.3 Other Techniques Used in the Field of Conducting Polymers;118 5.4;References;121 6;Chapter 4 Chemical and Electrochemical Syntheses of Conducting Polymers;131 7;Chapter 5 Thermodynamic Considerations;156 7.1;5.1 Neutral Polymer in Contact with an Electrolyte Solution;157 7.2;5.2 Charged Polymer in Contact with an Electrolyte Solution;161 7.3;5.3 Dimerization, Disproportionation and Ion Association Equilibria Within the Polymer Phase;171 7.4;References;173 8;Chapter 6 Redox Transformations and Transport Processes;174 8.1;6.1 Electron Transport;177 8.2;6.2 Ion Transport;193 8.3;6.3 Coupling of Electron and Ionic Charge Transport;200 8.4;6.4 Other Transport Processes;203 8.5;6.5 Effect of Film Structure and Morphology;206 8.6;6.6 Relaxation and Hysteresis Phenomena;213 8.7;6.7 Measurements of the Rate of Charge Transport;222 8.8;References;223 9;Chapter 7 Applications of Conducting Polymers;229 9.1;7.1 Material Properties of Conducting Polymers;229 9.2;7.2 Applications of Conducting Polymers in Various Fields of Technologies;231 9.3;References;259 10;Chapter 8 Historical Background (Or: There Is Nothing New Under the Sun);268 11;About the Author;272 12;About the Editor;274 13;Name Index;275 14;Subject Index;277
ISBN 9783540759300
Artikelnummer 9783540759300
Medientyp E-Book - PDF
Auflage 2. Aufl.
Copyrightjahr 2008
Verlag Springer-Verlag
Umfang 282 Seiten
Sprache Englisch
Kopierschutz Digitales Wasserzeichen