Electrochemistry of Immobilized Particles and Droplets
E-Book
Electrochemistry of Immobilized Particles and Droplets
Immobilizing particles or droplets on electrodes is a novel and most powerful technique for studying the electrochemical reactions of three-phase systems. It gives access to a wealth of information, ranging from quantitative and phase analysis to thermodynamic and kinetic data of electrode processes. Three-phase electrodes with immobilized droplets provide information on the electrochemistry of redox liquids and of compounds dissolved in inert organic liquids. Such measurements allow the determination of the Gibbs energies of the transfer of cations and anions between immiscible solvents, and thus make it possible to assess the hydrophobicity of ions - a property that is of great importance for pharmaceutical applications, biological studies, and for many fields of chemistry.
The monograph gives, for the first time, a comprehensive overview of the results published in more than 300 papers over the last 15 years. The experiments are explained in detail, applications from many different fields are presented, and the theoretical basis of the systems is outlined.
The monograph gives, for the first time, a comprehensive overview of the results published in more than 300 papers over the last 15 years. The experiments are explained in detail, applications from many different fields are presented, and the theoretical basis of the systems is outlined.
1;Foreword;5 2;Preface;7 3;Contents;10 4;1 Earlier Developed Techniques;13 4.1;1.1 Solid Materials ;14 4.2;1.2 Immiscible Liquids and Solutions;21 5;2 Electrodes with Immobilized Partlcies and Dropiets - Tliree-Pliase Eiectrodes;23 6;3 The Experiment;31 6.1;3.1 Electrodes, Electrolytes and Electrochemical Cells ;31 6.2;3.2 Immobilization of Particles;35 6.3;3.3 Attachment of Droplets;37 6.4;3.4 The Electrochemical Measurement;41 7;4 Hyphenated Techniques;43 7.1;4.1 Optical Techniques and Spectroeiectrocliemistry ;44 7.2;4.2 Atomic Force Microscopy and Scanning Tunnelling IVIicroscopy;61 7.3;4.3. Electrochemical Quartz Crystal Microbalance;68 7.4;4.4 In Situ X-ray Diffraction;70 7.5;4.5 In Situ Calorimetry;74 8;5 Immobilized Particles;87 8.1;5.1 Metals and Alloys;89 8.2;5.2 Minerals and Pigments;93 8.3;5.3 Solid Solutions - identification and Quantitative Analysis;110 8.4;5.4 Organometallics and Organic Compounds;119 8.5;5.5 Electrochemically Initiated Chemical Reactions of Solid Particles ;136 8.6;5.6 Assessing Structure-Property Relationships;146 8.7;5.7 Assessing Kinetic Properties of Electrochemical Dissolution Reactions;153 8.8;5.8 The Electrochemistry of Single Particles;159 8.9;5.9 Chemical and Enzymatic Conversion of immobiiized Particles ;161 8.10;5.10 The Screening of Electrocatalysts;165 8.11;5.11 Theoretical Aspects of the Voltammetry of Immobilized Particles;167 9;6 Immobilized Droplets;195 9.1;6.1 The Electrochemistry of Redox Liquids;199 9.2;6.2 The Electrochemistry of Compounds Dissolved in Droplets;221 9.3;6.3 Theoretical Models for the Voltammetry of Immobilized Droplets;239 10;7 Bibliography;267 11;Subject Index;297
Scholz, F.
Schröder, U.
Gulaboski, R.
| ISBN | 9783540261902 |
|---|---|
| Artikelnummer | 9783540261902 |
| Medientyp | E-Book - PDF |
| Auflage | 2. Aufl. |
| Copyrightjahr | 2005 |
| Verlag | Springer-Verlag |
| Umfang | 290 Seiten |
| Sprache | Englisch |
| Kopierschutz | Digitales Wasserzeichen |
