Electrochemistry of Immobilized Particles and Droplets

Electrochemistry of Immobilized Particles and Droplets

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Immobilizing particles or droplets on electrodes is a novel and most powerful technique for studying the electrochemical reactions of three-phase systems. It gives access to a wealth of information, ranging from quantitative and phase analysis to thermodynamic and kinetic data of electrode processes. Three-phase electrodes with immobilized droplets provide information on the electrochemistry of redox liquids and of compounds dissolved in inert organic liquids. Such measurements allow the determination of the Gibbs energies of the transfer of cations and anions between immiscible solvents, and thus make it possible to assess the hydrophobicity of ions - a property that is of great importance for pharmaceutical applications, biological studies, and for many fields of chemistry.
The monograph gives, for the first time, a comprehensive overview of the results published in more than 300 papers over the last 15 years. The experiments are explained in detail, applications from many different fields are presented, and the theoretical basis of the systems is outlined.



Earlier Developed Techniques
Electrodes with Immobilized Particles and Droplets - Three-Phase Electrodes
The Experiment
Hyphenated Techniques
Immobilized Particles
Immobilized Droplets.
ISBN 978-3-642-06032-8
Artikelnummer 9783642060328
Medientyp Buch
Copyrightjahr 2010
Verlag Springer, Berlin
Umfang XIII, 290 Seiten
Abbildungen XIII, 290 p.
Sprache Englisch