Organozinc Derivatives and Transition Metal Catalysts

Formation of C-C Bonds by Cross-coupling

Organozinc Derivatives and Transition Metal Catalysts

Formation of C-C Bonds by Cross-coupling

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Organozinc reagents are less reactive than Grignard reagents but they are much more chemoselective. Since the Negishi cross-coupling reaction developed by Ei-ichi Negishi, who was awarded the Nobel Price in chemistry in 2010, a number of cross-coupling reactions involving organozinc derivatives and transition metal catalysts (Pd, Ni, Fe, Co, Cu, ...) has been tuned up to form C-C bonds. This book on "Organozinc derivatives and transition metal catalysts" has been written by experts in the field and is a complement to the book entitled "Grignard reagents and transition metal catalysts" (a De Gruyter book, edited by J. Cossy).

Grignard reagents or organozinc reagents, that is the question? From a given substrate, what is the best organometallic reagent and the best transition metal to form a C-C bond by using a cross-coupling reaction? The solution might be found in these two books.

ISBN 9783110728774
Artikelnummer 9783110728774
Medientyp Buch
Copyrightjahr 2023
Verlag De Gruyter
Umfang X, 212 Seiten
Abbildungen 18 b/w and 273 col. ill., 2 b/w tbl.
Sprache Englisch