S Sulfur-Nitrogen Compounds
Part 10a: Compounds with Sulfur of Oxidation Number II
S Sulfur-Nitrogen Compounds
Part 10a: Compounds with Sulfur of Oxidation Number II
The present volume describes acyclic Sulfur-nitrogen compounds with sulfur of the oxida tion number II. The first chapter deals with sulfur imide (S=NH), N-organyl-sulfur imides (S=NR, R = or ganyl), and metal complexes of sulfur imides. N-Organyl-sulfur imides have not been isolated, but they can be trapped, for example, by cycloaddition and stabilized by coordination to transi tion metals. 11 The following chapter present a detailed survey of other 8 -N compounds with one coordinate sulfur, e.g., dithionitrous acid (S=N-SH) and derivatives, the salts of the dithionitryl ion (1 +) ([S=N=S]+), and N-thionitroso-diorganyl-amines (S=NNR , R = organyl). Only the reac 2 tions of [S=N=S]+ AsF5, among the known [S=N=S]+ salts, have been extensively studied. Cycloadditions with alkenes and triple bonded compounds produce 1 ,3,2-dithiazolium salts and their derivatives. S=NN(CH )z and S=NN(C H )z form transition metal complexes. The 3 6 5 Iigand is coordinated via the S atom in a monodentate manner.
3 Dithionitrous Acid and Derivatives
4 Salts of the Dithionitryl Ion (1+), [S=N=S]+
5 Dinitrogen Sulfide, SNN
6 N-Thionitroso-diorganylamines and Derivatives
7 Thiohydroxylamine and Derivatives
8 Thiooximes and Derivatives
9 Thiofulminic Acid and Derivatives
10 Isohypothiocyanous Acid Ion (1?), OCNS?
11 Thionitrous Acid and Derivatives
12 Sulfur Amide Halogenides and Derivatives
13 Sulfur Amide Hydroxide Derivatives, N,N-Substituted Amino-organyloxy-sulfanes
14 S-Phosphorus-Substituted Thiohydroxylamines and Derivatives
Physical Constants and Conversion Factors.
1 Sulfur Imide and Derivatives
2 Disulfur Nitride, Nitrogen Disulfide, SNS3 Dithionitrous Acid and Derivatives
4 Salts of the Dithionitryl Ion (1+), [S=N=S]+
5 Dinitrogen Sulfide, SNN
6 N-Thionitroso-diorganylamines and Derivatives
7 Thiohydroxylamine and Derivatives
8 Thiooximes and Derivatives
9 Thiofulminic Acid and Derivatives
10 Isohypothiocyanous Acid Ion (1?), OCNS?
11 Thionitrous Acid and Derivatives
12 Sulfur Amide Halogenides and Derivatives
13 Sulfur Amide Hydroxide Derivatives, N,N-Substituted Amino-organyloxy-sulfanes
14 S-Phosphorus-Substituted Thiohydroxylamines and Derivatives
Physical Constants and Conversion Factors.
Baumann, Norbert
Fachmann, Hans-Jürgen
Jotter, Reimund
Kubny, Alfons
ISBN | 978-3-662-06353-8 |
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Artikelnummer | 9783662063538 |
Medientyp | Buch |
Auflage | 8. Aufl. |
Copyrightjahr | 2013 |
Verlag | Springer, Berlin |
Umfang | XXIV, 324 Seiten |
Abbildungen | XXIV, 324 p. 1 illus. in color. |
Sprache | Englisch |