Science of Synthesis: Asymmetric Organocatalysis Vol. 2
Bronsted Base and Acid Catalysts, and Additional Topics
E-Book
Science of Synthesis: Asymmetric Organocatalysis Vol. 2
Bronsted Base and Acid Catalysts, and Additional Topics
Asymmetric Organocatalysis 2 from the Science of Synthesis series gives an authoritative, broad overview of the field, compiled by 3 8 experts, as well as a critical presentation of the best organocatalytic and related methodologies available today for practical as ymmetric synthesis. It provides alternative, greener syntheses with simple and easily used catalysts helping avoid the use of expens ive and/or toxic metals. The reference work covers all the catalysts and reactions within the activation modes Brønsted base catalys is and Brønsted acid catalysis. Typical or general experimental procedures as well as mechanistic, technical and theoretical aspects are included, allowing the reader to clearly see how simple, clean and efficient this chemistry is. // The content of this e-book w as originally published in December 2011.
1;Science of Synthesis: Asymmetric Organocatalysis 2 - Brønsted Base and Acid Catalysts, and Additional Topics;11.1;Organizational Structure of Science of Synthesis;21.2;Science of Synthesis Reference Library;31.3;Title page;51.4;Imprint;71.5;Preface;81.6;Asymmetric Organocatalysis Volumes;101.7;Abstracts;121.8;Overview;241.9;Table of Contents;261.10;2.1 Brønsted Bases;481.10.1;2.1.1 Chiral Guanidine and Amidine Organocatalysts;481.10.1.1;2.1.1.1 Synthesis of 2-Aminoacetonitriles;491.10.1.1.1;2.1.1.1.1 Catalytic Asymmetric Strecker Reactions;491.10.1.2;2.1.1.2 Synthesis of Chiral Alcohols;501.10.1.2.1;2.1.1.2.1 Catalytic Nitroaldol (Henry) Reactions;501.10.1.2.1.1;2.1.1.2.1.1 Nitroaldol Reactions with a-Chiral Aldehydes;531.10.1.2.1.2;2.1.1.2.1.2 Nitroaldol Reactions with a-Keto Esters;541.10.1.2.2;2.1.1.2.2 Catalytic Asymmetric Aldol Reactions;551.10.1.2.2.1;2.1.1.2.2.1 Aldol Reactions with Dihalofuran-2(5H)-ones;571.10.1.3;2.1.1.3 Synthesis of Chiral Amines;591.10.1.3.1;2.1.1.3.1 Catalytic Asymmetric Nitro-Mannich-Type Reactions;591.10.1.3.1.1;2.1.1.3.1.1 Nitro-Mannich-Type Reactions with Nitroacetates;631.10.1.3.1.2;2.1.1.3.1.2 Nitro-Mannich-Type Reactions with a-Substituted Nitroacetates;641.10.1.3.2;2.1.1.3.2 Catalytic Asymmetric Mannich-Type Reactions;651.10.1.4;2.1.1.4 Synthesis of Chiral Nitroalkanes;671.10.1.4.1;2.1.1.4.1 Catalytic Asymmetric Michael Reactions;671.10.1.4.1.1;2.1.1.4.1.1 Michael Reactions with ß-Keto Esters;691.10.1.4.1.2;2.1.1.4.1.2 Michael Reactions with Phenols;711.10.1.4.1.3;2.1.1.4.1.3 Michael Reactions with Nitroalkanes;721.10.1.4.1.4;2.1.1.4.1.4 Michael Reactions with 4,7-Dihydroindoles;731.10.1.5;2.1.1.5 Synthesis of Chiral Epoxy Ketones;751.10.1.5.1;2.1.1.5.1 Catalytic Asymmetric Nucleophilic Epoxidation Reactions;751.10.1.6;2.1.1.6 Synthesis of Chiral Hydrazines;761.10.1.6.1;2.1.1.6.1 Catalytic Asymmetric Amination Reactions;761.10.1.7;2.1.1.7 Synthesis of Chiral Phosphonates and Phosphine Oxides;781.10.1.7.1;2.1.1.7.1 Catalytic Asymmetric 1,4-Addition Reactions;781.10.1.7.1.1;2.1.1.7.1.1 1,4-Addition Reactions with Phosphites;781.10.1.7.1.2;2.1.1.7.1.2 1,4-Addition Reactions with Phosphine Oxides;791.10.1.8;2.1.1.8 Synthesis of Chiral d-Lactones;801.10.1.8.1;2.1.1.8.1 Catalytic Asymmetric Inverse-Electron-Demand Hetero-Diels--Alder Reactions;801.10.1.9;2.1.1.9 Synthesis of Chiral Pyrrolidines;831.10.1.9.1;2.1.1.9.1 Catalytic Asymmetric [3 + 2]-Cycloaddition Reactions;831.10.1.10;2.1.1.10 Synthesis of Chiral a-Keto Esters;841.10.1.10.1;2.1.1.10.1 Catalytic Asymmetric Claisen Rearrangement Reactions;841.10.2;2.1.2 Cinchona Alkaloid Organocatalysts;881.10.2.1;2.1.2.1 Nucleophilic Catalysis;891.10.2.1.1;2.1.2.1.1 Asymmetric Reactions with Ketenes;901.10.2.1.1.1;2.1.2.1.1.1 Synthesis of ß-Lactones;901.10.2.1.1.2;2.1.2.1.1.2 Intramolecular Synthesis of ß-Lactones;911.10.2.1.1.3;2.1.2.1.1.3 Synthesis of ß-Lactams;921.10.2.1.1.4;2.1.2.1.1.4 Synthesis of ß-Oxo Amides;931.10.2.1.1.5;2.1.2.1.1.5 Asymmetric Synthesis of a-Halogenated Esters;941.10.2.1.1.6;2.1.2.1.1.6 Cycloaddition of Ketenes and N-Thioacylimines;951.10.2.1.2;2.1.2.1.2 Asymmetric Morita--Baylis--Hillman Reactions;961.10.2.1.2.1;2.1.2.1.2.1 Synthesis of Hydroxy Acrylates;971.10.2.1.2.2;2.1.2.1.2.2 Synthesis of Sulfonamido Enones;981.10.2.1.3;2.1.2.1.3 Enantioselective Protonation;991.10.2.1.3.1;2.1.2.1.3.1 Thiol Addition to Alkyl(silyl)ketenes;991.10.2.1.4;2.1.2.1.4 Asymmetric Cyanation of Simple Ketones;1001.10.2.1.4.1;2.1.2.1.4.1 Synthesis of Cyanohydrin Carbonates;1001.10.2.1.5;2.1.2.1.5 Asymmetric Conjugate Additions;1011.10.2.1.5.1;2.1.2.1.5.1 Synthesis of tert-Butyl Cyclopropanecarboxylates;1021.10.2.1.5.2;2.1.2.1.5.2 Reaction of Indole with Morita--Baylis--Hillman Adducts;1021.10.2.1.5.3;2.1.2.1.5.3 Reaction of Furan-2-ones with Morita--Baylis--Hillman Adducts;1031.10.2.1.6;2.1.2.1.6 Asymmetric Electrophilic Halo
| ISBN | 9783131790118 |
|---|---|
| Artikelnummer | 9783131790118 |
| Medientyp | E-Book - PDF |
| Copyrightjahr | 2014 |
| Verlag | Georg Thieme Verlag KG |
| Umfang | 1010 Seiten |
| Sprache | Deutsch, Englisch |
| Kopierschutz | Digitales Wasserzeichen |
