1;Science of Synthesis: Knowledge Updates 2016/2;12;Title Page;63;Copyright;84;Preface;95;Abstracts;116;Science of Synthesis Knowledge Updates 2016/2;197;Table of Contents;218;1.2.7 Radical-Based Palladium-Catalyzed Bond Constructions;358.1;1.2.7.1 Method 1: Reactions Involving Palladium(I) Species;358.1.1;1.2.7.1.1 Variation 1: Synthesis of Organometallic Palladium(I) Complexes;358.1.2;1.2.7.1.2 Variation 2: Reactions Involving Palladium(I) Precatalysts;428.1.3;1.2.7.1.3 Variation 3: Cross-Coupling Reactions;508.1.4;1.2.7.1.4 Variation 4: Carbonylation Reactions;618.1.5;1.2.7.1.5 Variation 5: Cyclization Reactions;768.1.6;1.2.7.1.6 Variation 6: Atom-Transfer Reactions;828.2;1.2.7.2 Method 2: Reactions Involving Palladium(III) Species;968.2.1;1.2.7.2.1 Variation 1: Synthesis of Organometallic Palladium(III) Complexes;968.2.2;1.2.7.2.2 Variation 2: C-H Activation Reactions Involving Palladium(III);1068.2.3;1.2.7.2.3 Variation 3: C-F Bond-Constructing Reactions Involving Palladium(III);1138.2.4;1.2.7.2.4 Variation 4: Reactions Involving Phenyl or Benzoyl Radicals;1168.2.5;1.2.7.2.5 Variation 5: Asymmetric Aza-Claisen Rearrangements;1268.3;1.2.7.3 Method 3: Reactions Involving Palladium(I) and Palladium(III) Species;1298.4;1.2.7.4 Method 4: Miscellaneous Reactions;1329;2.11.15 C(sp3)-H Functionalization by Allylic C-H Activation of Zirconocene Complexes;1479.1;2.11.15.1 Method 1: Synthesis of Conjugated Dienes from Nonconjugated Dienes;1529.1.1;2.11.15.1.1 Variation 1: From Nonheteroatom-Substituted Alkenes;1529.1.2;2.11.15.1.2 Variation 2: From Nonconjugated Dienes Bearing an Alkoxy Substituent;1539.2;2.11.15.2 Method 2: Synthesis of Trienes;1569.3;2.11.15.3 Method 3: Synthesis of Homoallylic Alcohols;1579.3.1;2.11.15.3.1 Variation 1: From Acid Chlorides without Ligand Exchange;1579.3.2;2.11.15.3.2 Variation 2: From Acid Chlorides with Ligand Exchange;1589.3.3;2.11.15.3.3 Variation 3: From Aldehydes without Ligand Exchange;1609.3.4;2.11.15.3.4 Variation 4: From Aldehydes with Ligand Exchange;1629.4;2.11.15.4 Method 4: Diastereoselective Synthesis of Homoallylic Amines;1639.5;2.11.15.5 Method 5: Diastereoselective Synthesis of 1,4-Homoallylic Diols;1649.5.1;2.11.15.5.1 Variation 1: From Grignard Reagents;1649.5.2;2.11.15.5.2 Variation 2: From Terminal Alkenes;1669.6;2.11.15.6 Method 6: Synthesis of 1,2-Disubstituted Cyclopropanols;1679.7;2.11.15.7 Method 7: Synthesis of Substituted Allylic Derivatives from Unsaturated Fatty Alcohols;1679.8;2.11.15.8 Method 8: Selective Reduction of the Double Bond of ?-Ene Dihydrofurans and Dihydropyrans;1699.9;2.11.15.9 Method 9: Synthesis of Acyclic Fragments Possessing an All-Carbon Quaternary Stereogenic Center;1709.9.1;2.11.15.9.1 Variation 1: From ?-Ene Cyclopropanes;1709.9.2;2.11.15.9.2 Variation 2: From Alkylidenecyclopropanes;1739.9.3;2.11.15.9.3 Variation 3: From ?-Alkenylcyclopropanes Bearing a Leaving Group;17610;2.11.16 Synthesis and Reactivity of Heteroatom-Substituted Vinylzirconocene Derivatives and Hetarylzirconocenes;18110.1;2.11.16.1 General Preparation of Vinylzirconocene Derivatives;18210.2;2.11.16.2 General Reactivity of Vinylzirconocene Derivatives;18410.3;2.11.16.3 Preparation of Vinylzirconocene Derivatives from Heteroatom-Substituted Alkenes;18510.3.1;2.11.16.3.1 Method 1: From Alkenyl Halides;18610.3.2;2.11.16.3.2 Method 2: From Aryl Halides;18810.3.3;2.11.16.3.3 Method 3: From Enol Sulfonates;19210.3.4;2.11.16.3.4 Method 4: From Enol Ethers and Silyl Enol Ethers;19410.3.5;2.11.16.3.5 Method 5: From Sulfides, Sulfoxides, and Sulfones;19610.3.6;2.11.16.3.6 Method 6: From Carbamates;20010.3.7;2.11.16.3.7 Method 7: From Dienyl Systems;20211;2.12.17 The Role of Solvents and Additives in Reactions of Samarium(II) Iodide and Related Reductants;21111.1;2.12.17.1 Synthesis of Samarium(II) Reductants;21111.1.1;2.12.17.1.1 Samarium(II) Iodide;21211.1.1.1;2.12.17.1.1.1 Method 1: Synthesis in Tetrahydrofuran from Samarium an