1;Preface to the Series Synthetic Methods of Organometallic and Inorganic Chemistry
;5
2;Preface to Volume 10;7
3;Contents;8
4;Chapter 1: Amido Ligands in Coordination
Chemistry;15
4.1;1.1 Introduction;16
4.2;1.2 Amidinates;17
4.2.1;1.2.1 Ligands;17
4.2.2;1.2.2 Group 3 Metal and Lanthanide Complexes;18
4.2.3;1.2.3 Titanium and Zirconium Complexes;22
4.2.4;1.2.4 Complexes of the Vanadium Triad;26
4.2.5;1.2.5 Group 6 Metal and Later Transition Metal Complexes;28
4.3;1.3 Aminopyridinates;37
4.3.1;1.3.1 Ligands;37
4.3.2;1.3.2 Group 3 Metal and Lanthanide Complexes;39
4.3.3;1.3.3 Titanium and Zirconium Complexes;42
4.3.4;1.3.4 Complexes of the Vanadium Triad;48
4.3.5;1.3.5 Late Transition Metal Complexes;52
4.3.6;1.3.6 Heterobimetallics;54
5;Chapter 2: Hydroformylation and Hydroxycarbonylationof Alkenes; Formation of
C-N and C-C Bonds;56
5.1;2.1 Introduction;57
5.1.1;2.1.1 Synthesis of Tris(2-tern-butyl-4-methylphenyl) Phosphite
;57
5.1.2;2.1.2 The Hydroformylation Process;57
5.2;2.2 Asymmetric Hydroformylation of Styrene;59
5.2.1;2.2.1 Synthesis of Chiral Diphosphite 4 and its Complex HRh(4)(CO)2
;59
5.2.2;2.2.2 Asymmetric Hydroformylation;62
5.3;2.3 Palladium-Catalyzed Biphasic Hydroxycarbonylation of Alkenes;64
5.3.1;2.3.1 Preparation of Catalysts;64
5.3.2;2.3.2 Hydroxycarbonylation of Alkenes;65
5.4;2.4 Rhodium-Catalyzed Hydroformylation of Internal Olefins to Linear Aldehydes;67
5.4.1;2.4.1 Synthesis of Phosphine Ligands;68
5.4.2;2.4.2 Hydroformylation of Internal Alkenes;71
5.5;2.5 Application of (PP)Pd(Ar)(X) Catalysts in the Amination of Aryl
Bromides;72
5.5.1;2.5.1 Preparation of Catalysts;73
5.5.2;2.5.2 Palladium-Catalyzed Coupling of 2-Methoxyaniline (o-Anisidine) with Bromobenzene;74
5.6;2.6 Fast Heck Reaction using Bulky Monodentate Phosphorus Ligands;75
5.6.1;2.6.1 Synthesis of [(Phosphorus Amidite)Pd(t-Br)(p-C6H4CN)}2
;75
5.6.2;2.6.2 Palladium -Catalyzed Coupling of Styrene with Iodobenzene;76
6;Chapter 3: Rhodium Atom-Derived Catalysts in the Hydroformylation of 1,3-Dienes and Hydrosilylation of Aromatic
Nitriles;78
6.1;3.1 Introduction;79
6.2;3.2 Preparation of the Catalysts;79
6.2.1;3.2.1 Rhodium Solvated Metal Atoms: Catalyst A;79
6.2.2;3.2.2 Rhodium Dust: Catalyst B;80
6.2.3;3.2.3 Rhodium on y-Al203: Catalyst C;80
6.3;3.3 Hydroformylation of 1,3-Dienes with Rhodium Solvated Metal
Atoms - Catalyst A;80
6.4;3.4 Hydrosilylation of Aromatic Nitriles with Rhodium Dust and Rhodium on .
-Al203;82
7;Chapter 4: In Situ Catalysts in Enantioselective
Organic Transformations;86
7.1;4.1 Introduction;87
7.2;4.2 Enantioselective Hydrogenation of Z-(a)-N-Acetamidocinnamic
Acid;87
7.3;4.3 Enantioselective Hydrosilylation of Acetophenone with
Diphenylsilane;89
7.4;4.4 Enantioselective Synthesis of 4-Phenyldeltacyclene;90
8;Chapter 5:
Enantioselective Hydrogenations;92
8.1;5.1 Application of Solvias Josiphos Complexes for the Enantioselective Hydrogenation of Selected C=N, C=C and C=0
Functions;93
8.1.1;5.1.1 Introduction;93
8.1.2;5.1.2 Catalysts;93
8.1.3;5.1.3 Hydrogenation Procedure;94
8.1.4;5.1.4 Discussion;95
8.1.5;5.1.5 Conclusions;97
8.2;5.2 Immobilized Rh- and Ir-Diphosphine Complexes for
Enantioselective Hydrogenation;97
8.2.1;5.2.1 Introduction;97
8.2.2;5.2.2 Immobilization of Functionalized Diphosphine Ligands;98
8.2.3;5.2.3 Discussion of Immobilized Catalysts;100
8.2.4;5.2.4 Catalysts Precursors;1018.2.5;5.2.5 Hydrogenation Procedures;102
8.2.6;5.2.6 Discussion of Hydrogenation Reactions;103
8.2.7;5.3 Application of Cinchona-Modified Pt/Al203 Catalysts for the Enantioselective Hydrogenation of a
-Functionalized Ketones;104
8.2.7.1;5.3.1 Introduction;104
8.2.7.2;5.3.2 Catalyst Types and Pretreatment;104
8.2.7.3;5.3.3 Modifiers;105
8.2.7.4;5.3.4 Hydrogenation Procedure;106
8.2.7.5;5.3.5 Scope of the Method;107
9;Chapter 6: Application of Cp -Ruthenium(II) Catalysts in Stereoselective
Hydrogenation of Sorbic Acid;108
9.1;6.1 Introductio