1;Preface to the SeriesSynthetic Methods of Organometallic and Inorganic Chemistry;5 2;Preface to Volume 3;7 3;List of Abbreviations;8 4;Contents;9 5;Chapter 1: Introduction;13 6;Chapter 2: Acyclic Phosphorus(III) Compounds;18 6.1;2.1 Coordination Number 1;20 6.2;2.2 Coordination Number 2;40 6.3;2.3 Coordination Niimber 3;60 7;Chapter 3: Acyclic Phosphorus(V) Compounds;92 7.1;3.1 Coordination Number 3;93 7.2;3.2 Coordination Number 4;97 8;Chapter 4: Acyclic Compounds Containing Two or MorePhosphorus Atoms;118 8.1;Lithium Dinzethylphosphanomethanide, Bis(dimethylphosphano)methane -;119 8.2;Dichloro(diisopropylamino)phosphane, Dichloro(diphenylamino)phosphane,1,2-Bis(diisopropylamino)-1,2-dichlorodiphosphane - ;122 8.3;Pentanzethylcyclopentadienyl-Substituted Phosphanes, Diphosphanes, Cyclophosphanes,1,2- Diphosphaseleniranes, Diphosphenes -;125 8.4;2,4,6-Tri-tert.-butylphenylphosphane, (E)-1,2-Bis(2,4,6-tri-tert.-butylphenyl)diphosphene,(E)-1-(2,4,6-Trimethylphenyl)-2-(2,4,6-tri-tert.-butylpheny)diphosphene -;130 8.5;Bis(trimethylsil)phosphido(dicarbonyl)(pentamethylcyclopentadienyl)iron,(E)-1-[Dicarbonyl(pentamethylcyclopentadienyl)ferrio]-2-[2,4,6-tri-tert.-butylphenylidiphosphene - ;137 8.6;Bis(trimethylsyl)phosphido(dicarbonyl)(pentamethylcyclopentadienyl)iron,(E)-1-[Dicarbonyl(pentamethylcyclopentadienyl)ferrio]-2-[2,4,6-tri-tert.-butylphenyl]diphosphene - ;137 8.7;1,3-Bis(2,4,6-tri-tert.-butyphenyl)-1,3-diphosphaallene and its Precursors: Bis[(chloro)(2,4,6-tri-tert.-butylphenyl)phosphanolmethane,(E)-1,3-Bis(2,4,6-tri-tert.-butylphenyl)-3-chloro-1,3-diphosphapropene - ;152 8.8;A Lithium Diphosphaallyl Anion and its Precursor - ;155 8.9;Dichlorophosphano(tolyl)methylene(triphenyl)phosphorane, Dichlorophosphano-(ethyl)methylene(triphenyl)phosphorane - ;159 8.10;[Chloro(triphenylphosphoranylidene)methy]triphenylphosphonium Chloride,Hexaphenylcarbodiphosphorane - ;162 8.11;1,1,1,3,3,3-Hexaphenyltriphosphenium Tetrachloroaluminate, 1,1,1,3,3,3-Hexakis-(dimethylamino)triphosphenium Tetraphenylborate -;165 8.12;Further Acyclic Phosphorus Compounds Containing Two or More PhosphorusAtoms;167 9;Chapter: 5 Mono- and Polycyclic Phosphorus Compounds;168 9.1;3-tert.-Butyl-1-chloro-2-pheny1-1H-phosphirene - ;169 9.2;2,2,4,4-Tetrakis(diisopropylamino)-1,3,2X 5,4 X5-diazadiphosphete -;172 9.3;1,2,4-Diazaphosphole and its Precursor 1,3-Bis(dintethylamino)-2-phosphaallylicChloride -;174 9.4;1,1',3,3'-Tetrakis(dimethylamino)-1 X5,3 X5-diphosphete, 1,1',3,3',5,5'-Hexakis-(dimethylamino)-1X5,3X5,5X5-triphosphabenzene - ;177 9.5;4,4 ',5,5 '-Tetramethyl-2,2' -biphosphinine, cis-[Dichlorobis(4,4',5,5 '-tetramethyl-2,2'-biphosphinine)ruthenium(II)] - ;179 9.6;2,4,6,8-Tetra-tert.-butyl-1,3,5,7-tetraphosphapentacyclo[4.2.0.02,5.03,8.04,7]octane(2,4,6,8-Tetra-tert.-butyl-1,3,5,7-tetraphosphacubane) - ;184 9.7;Bis(n5-cyclopentadienyl){2,4-di-tert.-butyl-1,3-diphosphabicyclo[1.1.0]butane-2,4-diyl}zirconium - ;187 9.8;Synthesis of Exceedingly Strong Non-Ionic Bases Based on 2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane - ;189 9.9;Synthesis of Pentaoxyphosphoranes with Sulfur-Containing Eight-Membered Rings;193 9.10;Further Mono- and Polycyclic Phosphorus Compounds;199 10;Chapter 6: Compounds of Arsenic, Antimony, and Bismuth;200 10.1;Arsane, (1,2-Dimethoxyethane-0,0')lithiurn Arsanide,[1,2-Bis(dimethylamino)ethane-N,N']lithium Arsanide -;201 10.2;Tris(trimethylsilyl)arsane, -stibane, -bismuthane, (1,2-Dimethoxyethane-O,O' )-lithium Bis(trimethylsilyl)arsanide, -stibanide, -bismuthanide -;205 10.3;Diiodo(methy)arsane (Methylarsenic Diiodide) -;210 10.4;Triethylarsane -;212 10.5;Trimethylarsane oxide -;214 10.6;Dimethylantimony Bromide, Methylantimony Dibromide -;215 10.7;Triethylstibane, Triethylantimony Dibromide, Diethylantimony Bromide,Ethylantimony Dibromide, Ethylantimony Polymer, Pentaethylcyclopentastibane,Tetraethylcyclotetrastibane -;217 10.8;Trimesitylstibane, Mesitylantimony Dibromide, Tetramesitykyclotetrastibane Toluene -;