Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 8, 1997

Volume 8: Transition Metals Part 2

Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 8, 1997

Volume 8: Transition Metals Part 2

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Designed as a benchtop tool, the series includes detailed and reliable experimental procedures for the preparation of common but imp ortant starting compounds, organized according to the periodic table. Properties of the compounds and additional references are also provided. In most cases, no strict borderline has been drawn between inorganic and organometallic compounds. Instead, the material is conveniently presented so that for every group of elements, the various aspects of the chemistry are combined. Several hundred in ternational specialists with established expertise in their respective fields have contributed, resulting in proven and reliable pre parations. In view of the enormous growth of organometallic chemistry, Synthetic Methods of Organometallic and Inorganic Chemistry p rovides you with a balanced compilation of carefully selected and representative examples for all classes of compounds. // The conte nt of this e-book was originally published in 1997.

Wolfgang A. Herrmann, Georg Brauer

1;Preface to the Series Synthetic Methods of Organometallic and Inorganic Chemistry;6 2;Preface to Volume 8;8 3;Contents;9 4;Chapter 1: Complexes with Cyclic Ligands CnHn;11 4.1;1.1 Sandwich Complexes with Two Cyclic Ligands CnHn;12 4.2;1.2. Complexes with Three Identical Cyclic Ligands;25 4.3;1.3. Complexes with Mixed Aromatic Ligands;27 4.4;1.4 Complexes with Additional Ligands;40 5;Chapter 2: Complexes with One Cyclic Ligand CnHn;54 5.1;2.1 Carbonyl Complexes with One Cyclic Ligand;55 5.1.1;2.1.1 Synthesis;55 5.1.2;2.1.2. Reactions of Cyclopentadienyl Metal Carbonyl Complexes;56 5.1.3;2.1.3 Tetracarbonyl Complexes;57 5.1.4;2.1.4 Tricarbonyl Complexes;65 5.1.5;2.1.5 Di- and Monocarbonyl Complexes;77 5.2;2.2 Nitrosyl Complexes with Cyclic Ligands;86 5.3;2.3 Hydride Complexes with Cyclic Ligands;99 5.4;2.4 Halide Complexes with Cyclic Ligands;103 5.5;2.5 Sulfur Dioxide, Carbon Disulfide, Thiocarbonyl, and Related Complexes with Cyclic Ligands;122 5.6;2.6 Miscellaneous Complexes with Cyclic Ligands;131 5.6.1;2.6.1 ansa-Dimethylsilylbis(.5-cyclopentadienyl) Complexes of Titanium(IV) and Titanium(III);133 5.6.2;2.6.2 Fulvalenediyl Complexes;137 5.6.3;2.6 .3 Ansa-Complexes of Zirconium;148 5.6.4;2.6.4 Vanadium and Niobium Complexes;152 5.6.5;2.6.5 Chromium and Molybdenum Complexes;159 6;Chapter 3: Miscellaneous Complexes;168 6.1;3.1 Metal Complexes with Weakly Bonded Anions;169 6.1.1;3.1.1 General Considerations;169 6.1.2;3.1.2 Working Techniques;170 6.1.3;3.1.3 Carbony1(. 5-cyclopentadienyl)(tetrafluoroborato)molybdenurn and -tungsten Complexes;171 6.2;3.2 Complexes of Molybdenum and Tungsten;179 6.3;3.3 Heterobimetallic Complexes;184 6.4;3.4 Oxorhenium and Technetium Complexes;194 6.5;3.5 Complexes of Iron, Ruthenium, and Osmium;206 6.6;3.6 Complexes of Cobalt, Rhodium, and Iridium;213 6.7;3.7 Complexes of Nickel, Palladium, and Platinum;226 7;Index;239 8;List of Transition Metal Complexes in other Volumes;262
ISBN 9783131794819
Artikelnummer 9783131794819
Medientyp E-Book - ePUB
Copyrightjahr 2014
Verlag Georg Thieme Verlag KG
Umfang 266 Seiten
Sprache Englisch
Kopierschutz Digitales Wasserzeichen