The Jahn-Teller Effect

Fundamentals and Implications for Physics and Chemistry

The Jahn-Teller Effect

Fundamentals and Implications for Physics and Chemistry

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The Jahn-Teller effect continues to be a paradigm for structural instabilities and dynamical processes in molecules and in the condensed phase. Among the many important newer developments in the field one should mention cooperative phenomena in crystals, the general importance of pseudo-Jahn-Teller couplings for symmetry-lowering phenomena in molecular systems, non-adiabatic processes at conical intersections of potential energy surfaces and extensions of the basic theory in relation to the discovery of fullerenes and other icosahedral systems.

Written by leading international experts the aim of the present volume is to provide a survey of the state-of-the art in Jahn-Teller interactions at the interface of quantum chemistry and condensed matter physics, addressing both the non-expert scientist as well as those experts interested in expanding their knowledge into neighboring areas. 

Cast in form of a set of extensive and tutorial reviews - and thus suitable as a complement to available textbooks in the field - the following topics are dealt with in this book:

- Jahn-Teller effect and vibronic interactions: General theory

- Conical intersections and nonadiabatic dynamics in molecular processes

- Impurities; Spectroscopy of transition metal complexes

- Fullerenes and fullerides

- Jahn-Teller effect and molecular magnetism

- The cooperative Jahn-Teller effect and orbital ordering

- Jahn-Teller effect and high-Tc Superconductivity



Jahn-Teller effect and vibronic interactions: General theory
Recent Developments in the Jahn#x2013;Teller Effect Theory
Electronic Degeneracy and Vibrational Degrees of Freedom: The Permutational Proof of the Jahn#x2013;Teller Theorem
Group-Theoretical Analysis of Jahn#x2013;Teller Systems
Spin#x2013;Orbit Vibronic Coupling in Jahn#x2013;Teller and Renner Systems
Vibronic Coupling Constant and Vibronic Coupling Density
A New Method to Describe the Multimode Jahn#x2013;Teller Effect Using Density Functional Theory
Conical intersections and nonadiabatic dynamics in molecular processes
Second-Order Analysis of Conical Intersections: Applications to Photochemistry and Photophysics of Organic Molecules
Influence of the Geometric Phase and Non-Adiabatic Couplings on the Dynamics of the H+H Molecular System
Multi-Mode Jahn#x2013;Teller and Pseudo-Jahn#x2013;Teller Effects in Benzenoid Cations
On the Vibronic Interactions in Aromatic Hydrocarbon Radicals and Radical Cations
The Jahn#x2013;Teller Effect in Binary Transition Metal Carbonyl Complexes
Impurities; Spectroscopy of transition metal complexes
Jahn#x2013;Teller Effect for the 3d Ions (Orbital Triplets in a Cubic Crystal Field)
Constructing, Solving and Applying the Vibronic Hamiltonian
Instabilities in Doped Materials Driven by Pseudo Jahn#x2013;Teller Mechanisms
The Influence of Jahn#x2013;Teller Coupling on the High-Spin/Low-Spin Equilibria of Octahedral ML Polyhedra (M : Mn #x2212; Cu), with NiF as the Model Example
Fullerenes and fullerides
Following Jahn#x2013;Teller Distortions in Fulleride Salts by Optical Spectroscopy
Jahn#x2013;Teller Effects in Molecules on Surfaces with Specific Application to C
Jahn-Teller effect and molecular magnetism
Jahn#x2013;Teller Effect in Molecular Magnetism: An Overview
The Effect of Jahn#x2013;Teller Coupling in Hexacyanometalates on the Magnetic Anisotropy in Cyanide-Bridged Single-Molecule Magnets
The cooperative Jahn-Teller effect and orbital ordering
Cooperative Jahn#x2013;Teller Effect: Fundamentals, Applications, Prospects
Orbital Ordering Versus the Traditional Approach in the Cooperative Jahn#x2013;Teller Effect: A Comparative Study
Frustration Effect in Strongly Correlated Electron Systems with Orbital Degree of Freedom
Ultrasonic Consequences of the Jahn#x2013;Teller Effect
Long Range Cooperative and Local Jahn-Teller Effects in Nanocrystalline Transition Metal Thin Films
Jahn-Teller effect and high-Tc Superconductivity
Jahn#x2013;Teller Polarons, Bipolarons and Inhomogeneities. A Possible Scenario for Superconductivity in Cuprates
Polarons and Bipolarons in Jahn#x2013;Teller Crystals
Vibronic Polarons and Electric Current Generation by a Berry Phase in Cuprate Superconductors.
ISBN 978-3-662-51909-7
Artikelnummer 9783662519097
Medientyp Buch
Auflage Softcover reprint of the original 1st ed. 2009
Copyrightjahr 2016
Verlag Springer, Berlin
Umfang XXI, 915 Seiten
Abbildungen XXI, 915 p.
Sprache Englisch